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Title: Asymmetric total synthesis of (+)-swainsonine
Authors: Soontorn Chooprayoon
Chutima Kuhakarn
Patoomratana Tuchinda
Vichai Reutrakul
Manat Pohmakotr
Mahidol University
Keywords: Biochemistry, Genetics and Molecular Biology;Chemistry
Issue Date: 21-Jan-2011
Citation: Organic and Biomolecular Chemistry. Vol.9, No.2 (2011), 531-537
Abstract: A concise asymmetric synthesis of (+)-swainsonine (ent-1) is described starting from 2, which was readily prepared from commercially available l-glutamic acid. The method features installation of the indolizidine ring via an intramolecular cyclisation of α-sulfinyl carbanion as a key step. (+)-Swainsonine was obtained in 11.8% overall yield in 10 steps. © 2011 The Royal Society of Chemistry.
ISSN: 14770520
Appears in Collections:Scopus 2011-2015

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