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|Title:||Asymmetric total synthesis of (+)-swainsonine|
|Keywords:||Biochemistry, Genetics and Molecular Biology;Chemistry|
|Citation:||Organic and Biomolecular Chemistry. Vol.9, No.2 (2011), 531-537|
|Abstract:||A concise asymmetric synthesis of (+)-swainsonine (ent-1) is described starting from 2, which was readily prepared from commercially available l-glutamic acid. The method features installation of the indolizidine ring via an intramolecular cyclisation of α-sulfinyl carbanion as a key step. (+)-Swainsonine was obtained in 11.8% overall yield in 10 steps. © 2011 The Royal Society of Chemistry.|
|Appears in Collections:||Scopus 2011-2015|
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