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Title: Synthesis of high-molecular-weight poly(ε-caprolactone) catalyzed by highly active bis(amidinate) tin(ii) complexes
Authors: Khamphee Phomphrai
Chatyapha Pongchan-O
Wipavee Thumrongpatanaraks
Preeyanuch Sangtrirutnugul
Palangpon Kongsaeree
Manat Pohmakotr
Mahidol University
Keywords: Chemistry
Issue Date: 14-Mar-2011
Citation: Dalton Transactions. Vol.40, No.10 (2011), 2157-2159
Abstract: A series of bis(amidinate) tin(ii) complexes is synthesized and shown to rapidly polymerize ε-caprolactone (ε-CL) in the presence and absence of benzyl alcohol giving high-molecular-weight poly(ε-CL) (M n up to 160,600 Da). Ligands having electron donating groups were found to accelerate the polymerization by making the complex more nucleophilic. © 2011 The Royal Society of Chemistry.
ISSN: 14779234
Appears in Collections:Scopus 2011-2015

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