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|Title:||Synthesis of high-molecular-weight poly(ε-caprolactone) catalyzed by highly active bis(amidinate) tin(ii) complexes|
|Citation:||Dalton Transactions. Vol.40, No.10 (2011), 2157-2159|
|Abstract:||A series of bis(amidinate) tin(ii) complexes is synthesized and shown to rapidly polymerize ε-caprolactone (ε-CL) in the presence and absence of benzyl alcohol giving high-molecular-weight poly(ε-CL) (M n up to 160,600 Da). Ligands having electron donating groups were found to accelerate the polymerization by making the complex more nucleophilic. © 2011 The Royal Society of Chemistry.|
|Appears in Collections:||Scopus 2011-2015|
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