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Title: α,α-Difluoro-α-phenylsulfanyl-α- trimethylsilylmethane as "cF<inf>2</inf><sup>-</sup>" synthetic building block for the preparation of gem-difluoromethylenated cyclopentanols
Authors: Krisana Peewasan
Chutima Kuhakarn
Darunee Soorukram
Patoomratana Tuchinda
Vichai Reutrakul
Manat Pohmakotr
Mahidol University
Keywords: Biochemistry, Genetics and Molecular Biology;Chemistry;Environmental Science
Issue Date: 1-Mar-2012
Citation: Journal of Fluorine Chemistry. Vol.135, (2012), 367-372
Abstract: A general strategy for the preparation of gem-difluoromethylenated cyclopentanols has been demonstrated; it involves sequential fluoride-catalyzed nucleophilic addition of α,α-difluoro-α-phenylsulfanyl- α-trimethylsilylmethane (PhSCF 2 SiMe 3 ; 1) to homoallyl ketones followed by intramolecular radical cyclization. © 2011 Elsevier B.V. All rights reserved.
ISSN: 00221139
Appears in Collections:Scopus 2011-2015

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