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dc.contributor.authorSureerut Amnuaypornsrien_US
dc.contributor.authorShigeyuki Tokien_US
dc.contributor.authorBenjamin S. Hsiaoen_US
dc.contributor.authorJitladda Sakdapipanichen_US
dc.contributor.otherMahidol Universityen_US
dc.contributor.otherStony Brook Universityen_US
dc.identifier.citationPolymer (United Kingdom). Vol.53, No.15 (2012), 3325-3330en_US
dc.description.abstractSimultaneous synchrotron X-ray and stress-strain measurement of un-vulcanized natural rubber (NR) revealed that an upturn of stress at large strains and strain induced crystallization (SIC) are caused by endlinking pseudo network and entanglements. Higher pseudo network density of un-vulcanized NR shows higher modulus and larger fraction of SIC. At faster stretching speed, un-vulcanized NR shows higher stress and larger fraction of SIC. On the other hand, vulcanized NR show almost the same stress-strain relation and smaller fraction of SIC at faster stretching speed. Those different behaviors are governed by entanglements, endlinking pseudo networks in un-vulcanized NR and chemical bond networks, small amount of entanglements and endlinking networks in vulcanized NR. © 2012 Elsevier Ltd. All rights reserved.en_US
dc.rightsMahidol Universityen_US
dc.subjectMaterials Scienceen_US
dc.titleThe effects of endlinking network and entanglement to stress-strain relation and strain-induced crystallization of un-vulcanized and vulcanized natural rubberen_US
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