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Please use this identifier to cite or link to this item: http://repository.li.mahidol.ac.th/dspace/handle/123456789/16438
Title: Fractionation of lead in soils affected by smelter activities using a continuous-flow sequential extraction system
Authors: Namfon Tongtavee
Juwadee Shiowatana
Ronald G. McLaren
Mahidol University
Lincoln University, New Zealand
Keywords: Chemistry;Environmental Science
Issue Date: 15-Jul-2005
Citation: International Journal of Environmental Analytical Chemistry. Vol.85, No.8 (2005), 567-583
Abstract: A continuous-flow sequential extraction system was used to study the distribution of Pb, and its association with other elements (Fe, Al and Ca), in soils around a Pb smelter. Soil samples were analysed by a four-step continuous-flow sequential extraction procedure employing a modified Tessier/BCR scheme. Recoveries of Pb using the flow system (88-111%) were higher than those obtained using a conventional batch extraction system. There were also some differences in Pb distribution between fractions as determined using the two extraction systems. The most abundant fraction of Pb was extracted during the dissolution of soil oxides (Fe/Al). Extractograms (plots of concentration of elements vs . extractant volume/time) indicated that anthropogenic Pb was predominantly adsorbed onto Fe oxide surfaces in contaminated soils. In soil profiles, the highest amounts of Pb were found in the topsoil surface layers (0-5 cm) of the contaminated soils with only limited movement into subsurface layers. © 2005 Taylor & Francis Group Ltd.
URI: https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=33745058972&origin=inward
http://repository.li.mahidol.ac.th/dspace/handle/123456789/16438
ISSN: 10290397
03067319
Appears in Collections:Scopus 2001-2005

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