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Please use this identifier to cite or link to this item: http://repository.li.mahidol.ac.th/dspace/handle/123456789/17541
Title: Destannylative acylation of 1-[(2-methoxyethoxy)methoxy]-2- (phenylsulfonyl)-2-(tributylstannyl)cyclopropane: A novel route to 3- acylfurans
Authors: Manat Pohmakotr
Auntika Takampon
Mahidol University
Keywords: Biochemistry, Genetics and Molecular Biology;Chemistry;Pharmacology, Toxicology and Pharmaceutics
Issue Date: 24-Jun-1996
Citation: Tetrahedron Letters. Vol.37, No.26 (1996), 4585-4588
Abstract: Destannylative acylation of 1-[(2-methoxyethoxy)methoxy]-2- (phenylsulfonyl)-2-(tributylstannyl)cyclopropane (1) provided dihydrofurans 5 in good yields, which upon treatment with BF3.OEt2in CH2Cl2led to the formation of 3-acylfurans 6 in moderate yields. The reaction was proposed to proceed via the intramolecular Prins-type reaction of the oxonium intermediate 7.
URI: https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=0030600152&origin=inward
http://repository.li.mahidol.ac.th/dspace/handle/123456789/17541
ISSN: 00404039
Appears in Collections:Scopus 1991-2000

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