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Title: Samarium(II) iodide-mediated deoxygenative debromination of α-bromo-β-hydroxy (acetoxy) phenyl sulfones: Synthesis of α,β-unsaturated sulfones
Authors: Vichai Reutrakul
Suwatchai Jarussophon
Manat Pohmakotr
Yupa Chaiyasut
Saengvimon U-Thet
Patoomratana Tuchinda
Mahidol University
Keywords: Biochemistry, Genetics and Molecular Biology;Chemistry;Pharmacology, Toxicology and Pharmaceutics
Issue Date: 18-Mar-2002
Citation: Tetrahedron Letters. Vol.43, No.12 (2002), 2285-2288
Abstract: Deoxygenative debromination of α-bromo-β-hydroxy (acetoxy) phenyl sulfones with samarium(II) iodide led to substituted α,β-unsaturated sulfones in good to excellent yields. The E-isomer is the major product. A possible mechanism via an α-sulfonyl radical pathway is proposed. © 2002 Elsevier Science Ltd. All rights reserved.
ISSN: 00404039
Appears in Collections:Scopus 2001-2005

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