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Please use this identifier to cite or link to this item: http://repository.li.mahidol.ac.th/dspace/handle/123456789/20163
Title: Novel approaches for controlling stage structure of metal chloride-graphite intercalation compounds
Authors: H. Shioyama
M. B.H.M. Saman
A. Sanpanich
National Institute of Advanced Industrial Science and Technology
Standard and Industrial Research Institute of Malaysia Berhad
Mahidol University
Keywords: Engineering;Materials Science;Physics and Astronomy
Issue Date: 1-Jan-2002
Citation: Journal of Materials Research. Vol.17, No.12 (2002), 3190-3192
Abstract: Intercalation of EuCl3TbCl3, and AlCl3into graphite was carried out in the presence of chlorine. The observation of products by x-ray diffraction showed that the extent of chloride intercalation could be controlled through adjustment of the pressure of chlorine; increasing pressure tended to increase the extent of intercalation. In the case of EuCl3, the extent of intercalation varied to show a stage transition. In contrast, TbCl3intercalation gave a mixture of stage 2 or stage 4 graphite intercalation compound (GIC) and remaining graphite, where the extent of intercalation is revealed by the ratio of GIC to graphite. With respect to AlCl3intercalation, although the preparation of stage 1, 2, and 4 GICs was successful, stage 3 and 5 GICs could not be obtained.
URI: https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=0036968319&origin=inward
http://repository.li.mahidol.ac.th/dspace/handle/123456789/20163
ISSN: 08842914
Appears in Collections:Scopus 2001-2005

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