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Title: 1,2-Cyclic sulfamidates as versatile precursors to thiomorpholines and piperazines
Authors: Andrew J. Williams
Suda Chakthong
Diane Gray
Ron M. Lawrence
Timothy Gallagher
University of Bristol
GlaxoSmithKline plc, United Kingdom
Chulabhorn Research Institute
Mahidol University
Keywords: Biochemistry, Genetics and Molecular Biology;Chemistry
Issue Date: 20-Mar-2003
Citation: Organic Letters. Vol.5, No.6 (2003), 811-814
Abstract: (Matrix presented) 1,2-Cyclic sulfamidates undergo regiospecific nucleophilic displacement with either methyl thioglycolate or α-amino esters, followed by lactamization (thermal, base-mediated, or cyanide-catalyzed), to give thiomorpholin-3-ones and piperazin-2-ones.
ISSN: 15237060
Appears in Collections:Scopus 2001-2005

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