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Please use this identifier to cite or link to this item: http://repository.li.mahidol.ac.th/dspace/handle/123456789/20811
Title: α-sulfonyl radical initiated intramolecular tandem radical cyclization: Stereochemistries of a pair of doubly cyclized products
Authors: Lindsay T. Byrne
Manat Phomakotr
Chompoonut Poolsanong
Vichai Reutrakul
Brian W. Skelton
Allan H. White
University of Western Australia
Mahidol University
Keywords: Chemistry
Issue Date: 12-Aug-2003
Citation: Australian Journal of Chemistry. Vol.56, No.7 (2003), 715-717
Abstract: Room-temperature single-crystal X-ray structure determinations are recorded for trans-1,2,3,3a,9,9a-Hexahydro-cyclopenta[b]-1-benzothiapyran-4, 4-dioxide and its 3a-methyl analogue, minor products of the α-sulfonyl radical-initiated intramolecular tandem radical cyclization of H2C=CH(CH2)CRBrSO2Ph (R = H, CH3), confirming the assigned structures and rigorously establishing the trans relationship at the ring junctions.
URI: https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=0042093780&origin=inward
http://repository.li.mahidol.ac.th/dspace/handle/123456789/20811
ISSN: 00049425
Appears in Collections:Scopus 2001-2005

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