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|Title:||α-arylsulfanyl-α-fluoro carbenoids: Their novel chemistry and synthetic applications|
|Keywords:||Biochemistry, Genetics and Molecular Biology|
|Citation:||Organic Letters. Vol.6, No.24 (2004), 4547-4550|
|Abstract:||(Chemical equation presented) The bromine-magnesium exchange reactions of arylthiobromodifluoromethanes with Grignard reagents have been studied. Upon trapping with electrophiles, alkyl aryl sulfides and ketenedithioacetals are obtained. The reaction is proposed to occur via novel α-arylsulfanyl- α-fluoro carbenoids. The first examples of arylthiomethane multipole synthons are also reported.|
|Appears in Collections:||Scopus 2001-2005|
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