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Title: α-arylsulfanyl-α-fluoro carbenoids: Their novel chemistry and synthetic applications
Authors: Manat Pohmakotr
Winai Ieawsuwan
Patoomratana Tuchinda
Palangpon Kongsaeree
Samran Prabpai
Vichai Reutrakul
Mahidol University
Keywords: Biochemistry, Genetics and Molecular Biology
Issue Date: 25-Nov-2004
Citation: Organic Letters. Vol.6, No.24 (2004), 4547-4550
Abstract: (Chemical equation presented) The bromine-magnesium exchange reactions of arylthiobromodifluoromethanes with Grignard reagents have been studied. Upon trapping with electrophiles, alkyl aryl sulfides and ketenedithioacetals are obtained. The reaction is proposed to occur via novel α-arylsulfanyl- α-fluoro carbenoids. The first examples of arylthiomethane multipole synthons are also reported.
ISSN: 15237060
Appears in Collections:Scopus 2001-2005

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