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Title: Total synthesis of 6-deoxyclitoriacetal isolated from Stemona collinsae Craib.
Authors: Prapas Khorphueng
Jumreang Tummatorn
Amorn Petsom
Richard J.K. Taylor
Sophon Roengsumran
Mahidol University
University of York
Keywords: Biochemistry, Genetics and Molecular Biology;Chemistry;Pharmacology, Toxicology and Pharmaceutics
Issue Date: 14-Aug-2006
Citation: Tetrahedron Letters. Vol.47, No.33 (2006), 5989-5991
Abstract: A total synthesis of the rotenoid, 6-deoxyclitoriacetal, a cytotoxic natural product, was successfully achieved by using platinum-catalysed hydroarylation, Sharpless asymmetric dihydroxylation, regioselective IBX diol oxidation and stereoselective intramolecular keto-aldehyde pinacol coupling as the key steps. © 2006 Elsevier Ltd. All rights reserved.
ISSN: 00404039
Appears in Collections:Scopus 2006-2010

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