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|Title:||Total synthesis of 6-deoxyclitoriacetal isolated from Stemona collinsae Craib.|
Richard J.K. Taylor
University of York
|Keywords:||Biochemistry, Genetics and Molecular Biology;Chemistry;Pharmacology, Toxicology and Pharmaceutics|
|Citation:||Tetrahedron Letters. Vol.47, No.33 (2006), 5989-5991|
|Abstract:||A total synthesis of the rotenoid, 6-deoxyclitoriacetal, a cytotoxic natural product, was successfully achieved by using platinum-catalysed hydroarylation, Sharpless asymmetric dihydroxylation, regioselective IBX diol oxidation and stereoselective intramolecular keto-aldehyde pinacol coupling as the key steps. © 2006 Elsevier Ltd. All rights reserved.|
|Appears in Collections:||Scopus 2006-2010|
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