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Title: Two protocols for the conversion of biphenol to binaphthol: Synthesis of diospyrol
Authors: Nopporn Thasana
Somchai Pisutjaroenpong
Somsak Ruchirawat
Chulabhorn Research Institute
The Institute of Science and Technology for Research and Development, Mahidol University
Keywords: Chemistry
Issue Date: 3-May-2006
Citation: Synlett. No.7 (2006), 1080-1084
Abstract: The application of directed orthometallation (DoM), Fries rearrangement and transmetallation followed by allylation and cyclization is reported for the conversion of biphenol to binaphthol as a means for the synthesis of diospyrol. Furthermore, the same transformation can be accomplished by the reaction of the dienolate anion of an α,β-unsaturated amide with an aryne intermediate. © Georg Thieme Verlag Stuttgart.
ISSN: 09365214
Appears in Collections:Scopus 2006-2010

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