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|Title:||Two protocols for the conversion of biphenol to binaphthol: Synthesis of diospyrol|
Chulabhorn Research Institute
The Institute of Science and Technology for Research and Development, Mahidol University
|Citation:||Synlett. No.7 (2006), 1080-1084|
|Abstract:||The application of directed orthometallation (DoM), Fries rearrangement and transmetallation followed by allylation and cyclization is reported for the conversion of biphenol to binaphthol as a means for the synthesis of diospyrol. Furthermore, the same transformation can be accomplished by the reaction of the dienolate anion of an α,β-unsaturated amide with an aryne intermediate. © Georg Thieme Verlag Stuttgart.|
|Appears in Collections:||Scopus 2006-2010|
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