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Title: An orthorhombic polymorph of melaminium chloride hemihydrate
Authors: Umporn Athikomrattanakul
Chamras Promptmas
Martin Katterle
Uwe Schilde
Mahidol University
Universitat Potsdam
Keywords: Chemistry;Materials Science;Physics and Astronomy
Issue Date: 1-Dec-2007
Citation: Acta Crystallographica Section E: Structure Reports Online. Vol.63, No.5 (2007)
Abstract: Crystals of an ortho-rhom-bic polymorph of 2,4,6-triamino-1,3,5-triazin-1- ium chloride hemihydrate, C3H7N6+·Cl-·0. 5H2O, were obtained by cocrystallization experiments under aqueous acidic conditions (HCl, pH = 2). In the crystal structure, the melaminium ions, chloride anions and water mol-ecules are linked via hydrogen bonds. All H atoms of the melaminium cation are involved in hydrogen bonds. The chloride anions and the water mol-ecules lie on mirror planes. In the c direction, the melaminium ions are stacked by π-π inter-actions. © 2007 International Union of Crystallography. All rights reserved.
ISSN: 16005368
Appears in Collections:Scopus 2006-2010

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