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Title: Stereoselective sulfonate aldol reactions: Asymmetric synthesis of α,β-substituted β-hydroxy sulfonates
Authors: Wacharee Harnying
Wipaporn Kitisriworaphan
Manat Pohmakotr
Dieter Enders
Khon Kaen University
Mahidol University
Rheinisch-Westfalische Technische Hochschule Aachen
Keywords: Chemistry
Issue Date: 1-Oct-2007
Citation: Synlett. No.16 (2007), 2529-2532
Abstract: An efficient asymmetric synthesis of β-hydroxy sulfonates is described via stereocontrolled aldol reactions of sulfonates using 1,2:5,6-di-O- isopropylidene-α-D-allofuranose as the chiral auxiliary. The aldol reactions with aromatic aldehydes yielded predominantly syn adducts in very good yields and excellent diastereo- and enantiomeric excesses (de, ee ≥98%). © Georg Thieme Verlag Stuttgart.
ISSN: 09365214
Appears in Collections:Scopus 2006-2010

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