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|Title:||Application of the hypervalent iodine reagent to the synthesis of some pentasubstituted aporphine alkaloids|
Chulabhorn Research Institute
The Institute of Science and Technology for Research and Development, Mahidol University
|Citation:||Synlett. No.15 (2007), 2363-2366|
|Abstract:||The oxidative biaryl coupling of various N-substituted 1- benzyltetrahydroisoquinolines to the corresponding aporphines by the hypervalent iodine reagent was studied. The study sheds light on the unifying mechanism of the reaction illustrating the requirement of the p-p coupling via the six-membered transition state as the initial step. The finding was applied to the synthesis of some pentasubstituted aporphine alkaloids. © Georg Thieme Verlag Stuttgart.|
|Appears in Collections:||Scopus 2006-2010|
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