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Please use this identifier to cite or link to this item: http://repository.li.mahidol.ac.th/dspace/handle/123456789/24337
Title: Application of the hypervalent iodine reagent to the synthesis of some pentasubstituted aporphine alkaloids
Authors: Ratchanok Pingaew
Somsak Ruchirawat
Mahidol University
Chulabhorn Research Institute
The Institute of Science and Technology for Research and Development, Mahidol University
Keywords: Chemistry
Issue Date: 17-Sep-2007
Citation: Synlett. No.15 (2007), 2363-2366
Abstract: The oxidative biaryl coupling of various N-substituted 1- benzyltetrahydroisoquinolines to the corresponding aporphines by the hypervalent iodine reagent was studied. The study sheds light on the unifying mechanism of the reaction illustrating the requirement of the p-p coupling via the six-membered transition state as the initial step. The finding was applied to the synthesis of some pentasubstituted aporphine alkaloids. © Georg Thieme Verlag Stuttgart.
URI: https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=34948839846&origin=inward
http://repository.li.mahidol.ac.th/dspace/handle/123456789/24337
ISSN: 09365214
Appears in Collections:Scopus 2006-2010

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