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Crystal structures, spectro-structural correlation and structural pathways of eight [Cu(dpyam)<inf>2</inf>(NCO)][Y] complexes (dpyam = di-2-pyridylamine), Y = Br<sup>-</sup>, CF<inf>3</inf>SO<inf>3</inf><sup>-</sup>, BF<inf>4</inf><sup>-</sup>· dpyam, Cl<sup>-</sup>· 4H<inf>2</inf>O, NO<inf>3</inf><sup>-</sup>, PF<inf>6</inf><sup>-</sup>, ClO[...]. 56

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Crystal structures, spectro-structural correlation and structural pathways of eight [Cu(dpyam)<inf>2</inf>(NCO)][Y] complexes (dpyam = di-2-pyridylamine), Y = Br<sup>-</sup>, CF<inf>3</inf>SO<inf>3</inf><sup>-</sup>, BF<inf>4</inf><sup>-</sup>· dpyam, Cl<sup>-</sup>· 4H<inf>2</inf>O, NO<inf>3</inf><sup>-</sup>, PF<inf>6</inf><sup>-</sup>, ClO[...]. 0 1 1 2 2 8 1

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