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|Title:||Structural characterization of highly cis-1,4-polybutadiene: A comparing study in swollen and solid state using NMR technique|
Nagaoka University of Technology
|Keywords:||Chemistry;Materials Science;Physics and Astronomy|
|Citation:||Polymer Bulletin. Vol.46, No.6 (2001), 479-485|
|Abstract:||Commercial highly cis-1,4-polybutadiene was cured out by benzoyl peroxide from 3 to 12 phr in toluene solution. The structural characterization of resulting gel fraction or cured rubber was carried out in both swollen- and solid-state 13C-NMR measurements. The assignment of observed chemical shift proposed by using a shift factor method and empirical calculation using HOSE method.|
|Appears in Collections:||Scopus 2001-2005|
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