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Title: Efficient synthesis of alkyl 2,3-unsaturated glucopyranosides from glycals mediated by ytterbium(III) triflate-trialkyl aluminum
Authors: Pramchai Deelertpaiboon
Vichai Reutrakul
Suwatchai Jarussophon
Patoomratana Tuchinda
Chutima Kuhakarn
Manat Pohmakotr
Mahidol University
Keywords: Biochemistry, Genetics and Molecular Biology;Chemistry;Pharmacology, Toxicology and Pharmaceutics
Issue Date: 18-Nov-2009
Citation: Tetrahedron Letters. Vol.50, No.46 (2009), 6233-6235
Abstract: Treatment of glycals with trialkylaluminum in the presence of a catalytic amount of Yb(OTf)3leads to the corresponding alkyl 2,3-unsaturated glycosides in good to excellent yields. Reactions of protected glycals are achieved under very mild conditions. © 2009 Elsevier Ltd. All rights reserved.
ISSN: 00404039
Appears in Collections:Scopus 2006-2010

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