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|Title:||Efficient synthesis of alkyl 2,3-unsaturated glucopyranosides from glycals mediated by ytterbium(III) triflate-trialkyl aluminum|
|Keywords:||Biochemistry, Genetics and Molecular Biology;Chemistry;Pharmacology, Toxicology and Pharmaceutics|
|Citation:||Tetrahedron Letters. Vol.50, No.46 (2009), 6233-6235|
|Abstract:||Treatment of glycals with trialkylaluminum in the presence of a catalytic amount of Yb(OTf)3leads to the corresponding alkyl 2,3-unsaturated glycosides in good to excellent yields. Reactions of protected glycals are achieved under very mild conditions. © 2009 Elsevier Ltd. All rights reserved.|
|Appears in Collections:||Scopus 2006-2010|
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