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|Title:||Co- and counter-electroosmotic flow capillary electrophoresis of anionic phenols using UV and MS detection|
|Keywords:||Biochemistry, Genetics and Molecular Biology;Chemistry;Pharmacology, Toxicology and Pharmaceutics|
|Citation:||Journal of Liquid Chromatography and Related Technologies. Vol.32, No.15 (2009), 2176-2192|
|Abstract:||Co- and counter-electroosmotic flow (EOF) capillary electrophoresis (CE) of anionic phenols, using UV and mass spectrometry (MS) detection were investigated. The co-EOF CE-UV detection was performed by using hexadimethrine bromide (HDB) as an EOF modifier, which provided the separation in 6.2min. The counter-EOF CE-MS was obtained without HDB and coupling was achieved by sheath liquid interface. The CE-UV provided the better linearity (r20.99) than the CE-MS (r20.81), however, both methods gave comparable detection limits (5g/mL). CE-UV is efficient for the routine quantitative analysis, whereas CE-MS is useful for identification of the phenols.|
|Appears in Collections:||Scopus 2006-2010|
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