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Title: Study of the oscillation and luminol chemiluminescence in the H<inf>2</inf>O<inf>2</inf>-KSCN-CuSO<inf>4</inf>-NaOH system
Authors: Supavadee Kiatisevi
Steffen Maisch
Mahidol University
Universitat Stuttgart
Keywords: Chemistry;Physics and Astronomy
Issue Date: 20-Oct-2010
Citation: Chemical Physics Letters. Vol.499, No.1-3 (2010), 173-177
Abstract: Oscillations in redox potential and chemiluminescence of the H2O2-KSCN-CuSO4-NaOH system in the presence of luminol were examined. Parts of the mechanism proposed in the previous studies were evaluated by substitution of SCN-with CN-. The amplitude of the chemiluminescent oscillations was found to be strongly dependent on the initial luminol concentrations. In addition, the time-series ARMA (2;1)-analysis with Box-Jenkins algorithm were used to simulate the system and the result is well in accordance with the observed oscillations. © 2010 Elsevier B.V. All rights reserved.
ISSN: 00092614
Appears in Collections:Scopus 2006-2010

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