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|Title:||A stereoselective approach to bioactive secolignans: Synthesis of peperomin C and its analogues|
|Keywords:||Biochemistry, Genetics and Molecular Biology;Chemistry;Pharmacology, Toxicology and Pharmaceutics|
|Citation:||Tetrahedron. Vol.70, No.41 (2014), 7577-7583|
|Abstract:||© 2014 Elsevier Ltd. All rights reserved. A stereoselective approach to secolignans is described. The key synthetic strategy involves an asymmetric aldol reaction to control the creation of the stereogenic center at the β-carbon of the target secolignans. In the present work, peperomin C and its analogues, i.e., 2,6-didehydropeperomin C and 2-epi-peperomin C were successfully synthesized in good yields with high stereoselectivities.|
|Appears in Collections:||Scopus 2011-2015|
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