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Title: Palladium(II) complexes featuring bidentate pyridine-triazole ligands: Synthesis, structures, and catalytic activities for Suzuki-Miyaura coupling reactions
Authors: Sudarat Jindabot
Kriengkamol Teerachanan
Pech Thongkam
Supavadee Kiatisevi
Tossapol Khamnaen
Phairat Phiriyawirut
Sumate Charoenchaidet
Thanasat Sooksimuang
Palangpon Kongsaeree
Preeyanuch Sangtrirutnugul
Mahidol University
Thai Polyethylene Co.
Thailand National Metal and Materials Technology Center
Keywords: Biochemistry, Genetics and Molecular Biology;Chemistry;Materials Science
Issue Date: 1-Jan-2014
Citation: Journal of Organometallic Chemistry. Vol.750, (2014), 35-40
Abstract: Preparation of the Pd(II) complexes containing 2-(4-R-1,2,3-triazol-1-yl) pyridine [R = C6H5(1), NC5H4(2), n-C6H13(3)] were described. Crystal structures of 1 and 2 revealed a square planar geometry with bidentate ligand coordination to Pd using different N donor of the triazole ring. Catalytic studies indicated that 1-3 exhibited moderate to high activity for Suzuki-Miyaura coupling between aryl bromides and phenylboronic acid under mild and aerobic conditions. © 2013 Elsevier B.V. All rights reserved.
ISSN: 0022328X
Appears in Collections:Scopus 2011-2015

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