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Title: Synthesis of aromatic functionalized cage-rearranged silsesquioxanes (T<inf>8</inf>, T<inf>10</inf>, and T<inf>12</inf>) via nucleophilic substitution reactions
Authors: Supansa Chimjarn
Rungthip Kunthom
Prapassorn Chancharone
Rapheepraew Sodkhomkhum
Preeyanuch Sangtrirutnugul
Vuthichai Ervithayasuporn
Mahidol University
Keywords: Chemistry
Issue Date: 24-Nov-2014
Citation: Dalton Transactions. Vol.44, No.3 (2014), 916-919
Abstract: © The Royal Society of Chemistry 2015. Organic-inorganic hybrid nano-building blocks of aromatic nitro-, aldehyde-, and bromo-functionalized polyhedral oligomeric silsesquioxanes were easily prepared through nucleophilic substitutions, starting from the reactions between octakis(3-chloropropyl)octasilsesquioxane and phenoxide derivatives. These phenoxide anions not only supply the substitution functions to a silsesquioxane cage, but can also induce a cage-rearrangement leading to the formation of octa-, deca-, and dodecahedral silsesquioxane cages. This journal is
ISSN: 14779234
Appears in Collections:Scopus 2011-2015

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