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|Title:||Condensed mode cooling for ethylene polymerization: Part II. the effect of different condensable comonomers and hydrogen on polymerization rate|
Timothy F.L. McKenna
LCPP Laboratoire de Chimie et Procedes de Polymerisation
|Citation:||Macromolecular Chemistry and Physics. Vol.216, No.9 (2015), 985-995|
|Abstract:||© 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. A systematic analysis methodology is proposed in order to be able to evaluate the role and the significance of the impact of the physical and chemical phenomena during the gas phase ethylene copolymerization in presence of 1-pentene and 1-hexene comonomers in the gas phase composition. In addition, the effect of inert n-hexane on the instantaneous rate of gas phase ethylene polymerization in the absence and presence of 1-hexene comonomer and hydrogen is investigated. This, in turn, provides a novel insight on the counter-effects of the physical and chemical phenomena taking place simultaneously during the gas phase processes for ethylene polymerization in the industrially relevant conditions.|
|Appears in Collections:||Scopus 2011-2015|
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