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Title: F-THENA: a chiral derivatizing agent for the determination of the absolute configuration of secondary aromatic alcohols with a self-validating system
Authors: Kulvadee Dolsophon
Jakapun Soponpong
Jittra Kornsakulkarn
Chawanee Thongpanchang
Samran Prabpai
Palangpon Kongsaeree
Tienthong Thongpanchang
Mahidol University
Thailand National Center for Genetic Engineering and Biotechnology
Keywords: Biochemistry, Genetics and Molecular Biology;Chemistry
Issue Date: 1-Jan-2016
Citation: Organic and Biomolecular Chemistry. Vol.14, No.46 (2016), 11002-11012
Abstract: © The Royal Society of Chemistry. F-THENA is designed as an alternative fluorine-containing chiral derivatizing agent (CDA). The fluorine atom functions exclusively as a reporter which can directly sense an anisotropic effect from an aromatic substituent of a chiral alcohol. In combination with chemical shift differences from both19F NMR and1H NMR, the F-THENA method can successfully be used for determining the absolute configuration of chiral secondary aromatic alcohols with a self-validating system.
ISSN: 14770520
Appears in Collections:Scopus 2016-2017

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