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Title: Novel aminoalkyl tris-cyclometalated iridium complexes as cellular stains
Authors: A. Sansee
S. Meksawangwong
K. Chainok
K. J. Franz
M. Gál
L. O. Pålsson
W. Puniyan
R. Traiphol
R. Pal
F. Kielar
Naresuan University
Thammasat University
Duke University
Slovak University of Technology in Bratislava
University of Durham
Naresuan Univesity
Mahidol University
Keywords: Chemistry
Issue Date: 1-Jan-2016
Citation: Dalton Transactions. Vol.45, No.43 (2016), 17420-17430
Abstract: © 2016 The Royal Society of Chemistry. Herein we report the synthesis and investigation of the properties of two tris-cyclometalated luminescent iridium complexes. These complexes are the simple derivatives of fac-[Ir(ppy)3] bearing amino alkyl groups on one of the phenylpyridine rings. The complexes are highly emissive and exhibit structured emission peaks in aqueous solution while having only broad unstructured emission in organic solvents. The complexes have been shown to be taken up by NIH-3T3 and PC3 cells, where they localize in the lysosomes and remain emissive with lifetimes in the microsecond domain.
ISSN: 14779234
Appears in Collections:Scopus 2016-2017

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