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Title: Electrophilic Aromatic Formylation with Difluoro(phenylsulfanyl) methane
Authors: Nolan M. Betterley
Sopanat Kongsriprapan
Suppisak Chaturonrutsamee
Pramchai Deelertpaiboon
Panida Surawatanawong
Manat Pohmakotr
Darunee Soorukram
Vichai Reutrakul
Chutima Kuhakarn
Mahidol University
International Laboratories Corp.
Keywords: Chemical Engineering;Chemistry
Issue Date: 17-May-2018
Citation: Synthesis (Germany). Vol.50, No.10 (2018), 2033-2040
Abstract: © Georg Thieme Verlag Stuttgart New York. Difluoro(phenylsulfanyl)methane (PhSCF 2 H) was found to undergo a reaction with aromatic compounds mediated by SnCl 4, through a thionium intermediate characterized by NMR and TD-DFT analyses, leading to the formation of a mixture of S, S ′-diphenyl dithioacetal and aromatic aldehyde which, after oxidative hydrolysis, provides the aromatic aldehyde in good to excellent yields. The salient feature of the present work is the reaction of activated aromatic compounds containing a deactivating ester functional group, leading to the formylated products in good yields.
ISSN: 1437210X
Appears in Collections:Scopus 2018

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