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Title: Modifying interlayer space of montmorillonite with octakis(3-(1-methylimidazolium)propyl) octasilsesquioxane chloride
Authors: Vuthichai Ervithayasuporn
Supphachok Chanmungkalakul
Nut Churinthorn
Thapakorn Jaroentomeechai
Sasikarn Hanprasit
Rapheepraew Sodkhomkhum
Pusthira Kaewpijit
Suda Kiatkamjornwong
Chulalongkorn University
Mahidol University
Keywords: Earth and Planetary Sciences
Issue Date: 1-Apr-2019
Citation: Applied Clay Science. Vol.171, (2019), 6-13
Abstract: © 2019 Elsevier B.V. Highly water-soluble material of multi-imidazolium based silsesquioxane cages (material 2) is a promising candidate for modifying clay mineral interlayer space, which is successfully demonstrated by using montmorillonite. The modified montmorillonite can be easily prepared via cation exchange reaction between material 2 and sodium ions of montmorillonite, dispersed in an aqueous solution at room temperature. The modified montmorillonite formed a precipitate within a few seconds. A single layer of material 2 found to be intercalated in the modified montmorillonite with a maximum interlayer space (d-value) of 18 Å (1.8 nm) from 13 Å (1.3 nm) of the unmodified one was confirmed by transmission electron microscopy (TEM) and X-rays diffraction (XRD). Moreover, the percentage uptake and nature of incorporation of material 2 into montmorillonite layers were investigated by thermal gravimetric analyses (TGA), 29 Si NMR and FT-IR spectroscopies.
ISSN: 01691317
Appears in Collections:Scopus 2019

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