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Title: Facile and economical Miyaura borylation and one-pot Suzuki–Miyaura cross-coupling reaction
Authors: Phongsakorn Boontiem
Supavadee Kiatisevi
Mahidol University
Keywords: Chemistry;Materials Science
Issue Date: 1-Jun-2020
Citation: Inorganica Chimica Acta. Vol.506, (2020)
Abstract: © 2020 Elsevier B.V. Facile and economical method for Miyaura borylation reaction between B2pin2 and aryl bromides is reported. The catalytic system containing 2 mol% PdCl2(PPh3)2 and KOAc serves to enable borylations to occur under solvent-free and atmospheric conditions. The developed protocol can be applied to synthesize symmetrical and unsymmetrical biaryls via one-pot two-step Suzuki–Miyaura cross-coupling reaction and also offers the up-scalability.
ISSN: 00201693
Appears in Collections:Scopus 2020

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