Bunchuay T.Khianjinda T.Srisawat P.Tse Y.C.Gateley C.Beer P.D.Mahidol University2023-11-112023-11-112023-01-01Chemical Communications (2023)13597345https://repository.li.mahidol.ac.th/handle/20.500.14594/90994Ammonium-dibenzo[24]crown-8 [2]catenane functionalisation of a 3,5-bis-iodotriazole-pyridine motif produces a potent halogen bonding (XB) receptor capable of binding anions in aqueous-acetone solvent mixtures of up to 20% water. Exploiting the kinetically inert nature of the mechanically bonded cationic ammonium [2]catenane substituents, the XB receptor is demonstrated to exhibit superior anion recognition behaviour in comparison to labile sodium cation complexed bis-benzo[15]crown-5 XB and HB triazole-pyridine heteroditopic receptor analogues.ChemistryEnhanced anion recognition by ammonium [2]catenane functionalisation of a halogen bonding acyclic receptorArticleSCOPUS10.1039/d3cc03269h2-s2.0-851755399771364548X37901989