Intramolecular acylation of α-sulfinyl carbanion: a facile synthesis of (±)-pentenomycin I and (±)-epipentenomycin I.

Manat PohmakotrSupatara PopuangMahidol University2018-08-102018-08-101991-01-07Tetrahedron Letters. Vol.32, No.2 (1991), 275-278004040392-s2.0-0026068713https://repository.li.mahidol.ac.th/handle/20.500.14594/21993(±)-Pentenomycin I and (±)-epipentenomycin I were synthesized, starting from methyl 2,2-dimethyl-1,3-dioxolane-4-carboxylate. The key reaction involved the intramolecular acylation of α-sulfinyl carbanion and pyrolysis of the resulting product. © 1991.Mahidol UniversityBiochemistry, Genetics and Molecular BiologyChemistryPharmacology, Toxicology and PharmaceuticsIntramolecular acylation of α-sulfinyl carbanion: a facile synthesis of (±)-pentenomycin I and (±)-epipentenomycin I.ArticleSCOPUS10.1016/0040-4039(91)80874-6