Manat PohmakotrWinai IeawsuwanPatoomratana TuchindaPalangpon KongsaereeSamran PrabpaiVichai ReutrakulMahidol University2018-07-242018-07-242004-11-25Organic Letters. Vol.6, No.24 (2004), 4547-4550152370602-s2.0-10044224653https://repository.li.mahidol.ac.th/handle/20.500.14594/21117(Chemical equation presented) The bromine-magnesium exchange reactions of arylthiobromodifluoromethanes with Grignard reagents have been studied. Upon trapping with electrophiles, alkyl aryl sulfides and ketenedithioacetals are obtained. The reaction is proposed to occur via novel α-arylsulfanyl- α-fluoro carbenoids. The first examples of arylthiomethane multipole synthons are also reported.Mahidol UniversityBiochemistry, Genetics and Molecular BiologyArticleSCOPUS10.1021/ol048085m