Intramolecular acylation of α-sulfinyl carbanion a new general route to 5-methylene-2-cyclopentenones

Manat PohmakotrSirirat ChancharuneeMahidol University2018-10-122018-10-121984-01-01Tetrahedron Letters. Vol.25, No.37 (1984), 4141-4144004040392-s2.0-0142173082https://repository.li.mahidol.ac.th/handle/20.500.14594/30584A convenient synthesis of 5-methylene-2-cyclopentenones including Methylenomycin B involving the intramolecular acylation of α-sulfinyl carbanion followed by methylation and pyrolysis is described. © 1984.Mahidol UniversityBiochemistry, Genetics and Molecular BiologyChemistryPharmacology, Toxicology and PharmaceuticsIntramolecular acylation of α-sulfinyl carbanion a new general route to 5-methylene-2-cyclopentenonesArticleSCOPUS10.1016/S0040-4039(01)90204-7