Nitration-Oximization of Styrene Derivatives with tert-Butyl Nitrite: Synthesis of α-Nitrooximes

Napasawan ChumnanvejPraewpan KatrunManat PohmakotrVichai ReutrakulDarunee SoorukramChutima KuhakarnMahidol University2018-12-112019-03-142018-12-112019-03-142016-01-01Chinese Journal of Chemistry. Vol.34, No.8 (2016), 830-838161470651001604X2-s2.0-84964426949https://repository.li.mahidol.ac.th/handle/20.500.14594/43411Copyright © 2016 SIOC, CAS, Shanghai & WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim A highly efficient method for direct nitration-oximization of styrene derivatives using tert-butyl nitrite (t-BuONO) in DMSO was developed. The present method offers a convenient and practical approach for the synthesis of α-nitrooximes in moderate to high yields. The salient features entail mild reaction conditions, metal-free reagent, environmentally benign solvent and simple experimental procedure.Mahidol UniversityChemistryNitration-Oximization of Styrene Derivatives with tert-Butyl Nitrite: Synthesis of α-NitrooximesArticleSCOPUS10.1002/cjoc.201600167