Prapas KhorphuengJumreang TummatornAmorn PetsomRichard J.K. TaylorSophon RoengsumranMahidol UniversityUniversity of York2018-08-202018-08-202006-08-14Tetrahedron Letters. Vol.47, No.33 (2006), 5989-5991004040392-s2.0-33745726167https://repository.li.mahidol.ac.th/handle/123456789/22993A total synthesis of the rotenoid, 6-deoxyclitoriacetal, a cytotoxic natural product, was successfully achieved by using platinum-catalysed hydroarylation, Sharpless asymmetric dihydroxylation, regioselective IBX diol oxidation and stereoselective intramolecular keto-aldehyde pinacol coupling as the key steps. © 2006 Elsevier Ltd. All rights reserved.Mahidol UniversityBiochemistry, Genetics and Molecular BiologyChemistryPharmacology, Toxicology and PharmaceuticsTotal synthesis of 6-deoxyclitoriacetal isolated from Stemona collinsae Craib.ArticleSCOPUS10.1016/j.tetlet.2006.05.188