Significant stabilization of palladium by gold in the bimetallic nanocatalyst leading to an enhanced activity in the hydrodechlorination of aryl chlorides

Sangita KaranjitAtchaleeya JinasanEkasith SamsookRaghu N. DhitalKenichi MotomiyaYoshinori SatoKazuyuki TohjiHidehiro SakuraiOsaka UniversityMahidol UniversityTohoku UniversityInterdisciplinary Cluster for Cutting Edge ResearchJapan Science and Technology AgencyShinshu University2018-11-232018-11-232015-08-18Chemical Communications. Vol.51, No.64 (2015), 12724-127271364548X135973452-s2.0-84938247919https://repository.li.mahidol.ac.th/handle/20.500.14594/35695© The Royal Society of Chemistry 2015. The stabilization effect of Au towards Pd changed the reactivity of Pd in Au/Pd bimetallic nanoclusters, altering the reaction mechanism from homogeneous to heterogeneous in dechlorination reaction of aryl chlorides. This phenomenon was illustrated by the observed enhancement of the rate of reaction by in situ generated Au-rich bimetallic Au/Pd nanoclusters.Mahidol UniversityChemical EngineeringChemistryMaterials ScienceSignificant stabilization of palladium by gold in the bimetallic nanocatalyst leading to an enhanced activity in the hydrodechlorination of aryl chloridesArticleSCOPUS10.1039/c5cc04432d