Vichai ReutrakulVatcharin RukachaisirikulMahidol University2018-10-122018-10-121983-01-01Tetrahedron Letters. Vol.24, No.7 (1983), 725-728004040392-s2.0-0000086269https://repository.li.mahidol.ac.th/handle/20.500.14594/30447Alkylation of lithio fluoromethyl phenyl sulfoxide 2 gave the alkylated products in high yields. Pyrolysis of the products led to vinyl fluorides in excellent yields. The reaction of 2 with carbonyl compounds led to the corresponding β-hydroxy-α-fluoromethyl phenyl sulfoxides. Pyrolysis of some of the sulfoxides gave fluoromethylketones in moderate yields. © 1983.Mahidol UniversityBiochemistry, Genetics and Molecular BiologyChemistryPharmacology, Toxicology and PharmaceuticsFluoromethyl phenyl sulfoxide: Highly convenient syntheses of vinyl fluorides and fluoromethylketonesArticleSCOPUS10.1016/S0040-4039(00)81509-9