Pattaraporn Kim-LohsoontornYu Mi KimNavadol LaosiripojanaJoongmyeon BaeMahidol UniversityKorea Advanced Institute of Science & TechnologyKing Mongkuts University of Technology Thonburi2018-05-032018-05-032011-08-01International Journal of Hydrogen Energy. Vol.36, No.16 (2011), 9420-9427036031992-s2.0-79960901436https://repository.li.mahidol.ac.th/handle/123456789/11853Steam electrolysis (H 2 O → H 2 + 0.5O 2 ) was investigated in solid oxide electrolysis cells (SOECs). The electrochemical performance of GDC-impregnated Ni-YSZ and 0.5% wt Rh-GDC-impregnated Ni-YSZ was compared to a composite Ni-YSZ and Ni-GDC electrode using a three-electrode set-up. The electrocatalytic activity in electrolysis mode of the Ni-YSZ electrode was enhanced by GDC impregnation. The Rh-GDC-impregnated Ni-YSZ exhibited significantly improved performance, and the electrode exhibited comparable performance between the SOEC and SOFC modes, close to the performance of the composite Ni-GDC electrode. The performance and durability of a single cell GDC-impregnated Ni-YSZ/YSZ/LSM-YSZ with an H 2 electrode support were investigated. The cell performance increased with increasing temperature (700 °C-800 °C) and exhibited comparable performance with variation of the steam-to-hydrogen ratio (50/50 to 90/10). The durability in the electrolysis mode of the Ni-YSZ/YSZ/LSM-YSZ cell was also significantly improved by the GDC impregnation (200 h, 0.1 A/cm 2 , 800 °C, H 2 O/H 2 = 70/30). © 2011, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.Mahidol UniversityEnergyPhysics and AstronomyArticleSCOPUS10.1016/j.ijhydene.2011.04.199