Jirawat NarongthongSukanya NuasaenTeeraporn SuteewongPramuan TangboriboonratMahidol UniversityKing Mongkut's Institute of Technology Ladkrabang2018-11-232018-11-232015-04-01Colloid and Polymer Science. Vol.293, No.4 (2015), 1269-1274143515360303402X2-s2.0-84939960537https://repository.li.mahidol.ac.th/handle/20.500.14594/35703© 2015, Springer-Verlag Berlin Heidelberg. Hybrid hollow latex (HL) particles possessing poly(styrene-co-acrylic acid) (P(St/AA)) as the inner shell, poly(divinyl benzene) (PDVB) as the outer shell, and silica nanoparticles (SiNPs) as the stabilizer were conveniently prepared via the combined Pickering and seeded emulsion polymerizations. P(St/AA) particles (435 nm) were used as seeds, DVB as a swollen and crosslink monomer, 2,2′-azobis(2-methylpropionamidine) dihydrochloride as initiator, and SiNPs as Pickering stabilizer. Without core removal, solvent evaporation, and surface modification steps, the spherical, monodisperse, and non-collapsed HL-SiNPs particles (722 nm) with double shell polymer layer and a large void cavity (400 nm) were obtained. The presence of large cavity and double shell may enable these hybrid HL-SiNPs particles to be used as lightweight filler and/or white pigment in coatings.Mahidol UniversityChemical EngineeringChemistryMaterials ScienceArticleSCOPUS10.1007/s00396-015-3522-y