Phongsakorn BoontiemSupavadee KiatiseviMahidol University2020-03-262020-03-262020-06-01Inorganica Chimica Acta. Vol.506, (2020)002016932-s2.0-85080088425https://repository.li.mahidol.ac.th/handle/20.500.14594/53637© 2020 Elsevier B.V. Facile and economical method for Miyaura borylation reaction between B2pin2 and aryl bromides is reported. The catalytic system containing 2 mol% PdCl2(PPh3)2 and KOAc serves to enable borylations to occur under solvent-free and atmospheric conditions. The developed protocol can be applied to synthesize symmetrical and unsymmetrical biaryls via one-pot two-step Suzuki–Miyaura cross-coupling reaction and also offers the up-scalability.Mahidol UniversityChemistryMaterials ScienceArticleSCOPUS10.1016/j.ica.2020.119538