Thasanaporn UngpittagulPhonpimon WongmahasirikunKhamphee PhomphraiVidyasirimedhi Institute of Science and TechnologyMahidol University2020-08-252020-08-252020-07-07Dalton Transactions. Vol.49, No.25 (2020), 8460-847114779234147792262-s2.0-85087435171https://repository.li.mahidol.ac.th/handle/20.500.14594/57810© The Royal Society of Chemistry. Novel homoleptic and heteroleptic (guanidinate)tin(ii) complexes were successfully synthesized and structurally characterized. The first heteroleptic (guanidinato)tin(ii) alkoxide complex was synthesized but found to be unstable leading to the corresponding bis(guanidinate)tin(ii) complex. The catalytic activities of bis(guanidinate)tin(ii) complexes having different substituents at the nitrogen atoms (isopropyl (1), cyclohexyl (2), and p-tolyl (3)) were investigated in the ring-opening polymerization (ROP) of ϵ-caprolactone (ϵ-CL) and lactide (LA). The lone-pair electrons of the tin(ii) atom were proposed to act as an initiator similar to N-heterocyclic carbenes. Among the synthesized catalysts, complex 1 having less steric hindrance efficiently catalyzed both homo- A nd copolymerizations of ϵ-CL and LA giving high molecular weight cyclic polyesters. Transesterification was found to be the major contributor to the cyclization to cyclic polyesters. This journal isMahidol UniversityChemistryArticleSCOPUS10.1039/d0dt01115k