1,2-Carbonyl migration along the allylic framework: Synthesis of alkenylnaphthoquinones

Chulabhorn MahidolYongyut PinyopronpanitShuleewan RadviroongitChachanat ThebtaranonthYodhathai ThebtaranonthMahidol University2018-06-142018-06-141988-01-01Journal of the Chemical Society, Chemical Communications. No.20 (1988), 1382-1383002249362-s2.0-37049077339https://repository.li.mahidol.ac.th/handle/20.500.14594/15496Instead of undergoing a cyclopentenone annulation, the allylmalonate anion derived from the dicarboxylate (7) rearranges to vinylsuccinate (5), an application of which has led to a convenient synthesis of vinylnaphthoquinones (10).Mahidol UniversityBiochemistry, Genetics and Molecular Biology1,2-Carbonyl migration along the allylic framework: Synthesis of alkenylnaphthoquinonesArticleSCOPUS10.1039/C39880001382