Aryl iodides as strong inhibitors in gold and gold-based bimetallic quasi-homogeneous catalysis

Raghu Nath DhitalChoavarit KamonsatikulEkasith SomsookYoshinori SatoHidehiro SakuraiNational Institutes of Natural Sciences - Institute for Molecular ScienceJapan Science and Technology AgencyMahidol UniversityTohoku University2018-10-192018-10-192013-03-28Chemical Communications. Vol.49, No.25 (2013), 2542-25441364548X135973452-s2.0-84874618919https://repository.li.mahidol.ac.th/handle/123456789/31482The strong inhibitor effect of aryl iodides on the quasi-homogenous gold-catalyzed oxidation reaction was described. Aryl iodides were adsorbed on the exposed surface of Au clusters, which affected the accessibility of the nanoclusters to the reacting species and acted as strong inhibitors in catalysis. © 2013 The Royal Society of Chemistry.Mahidol UniversityChemical EngineeringChemistryMaterials ScienceAryl iodides as strong inhibitors in gold and gold-based bimetallic quasi-homogeneous catalysisArticleSCOPUS10.1039/c3cc39019e