Publication:
Interphase transfer of plasticizer between immiscible rubbers

dc.contributor.authorNawaphorn Kuhakongkiaten_US
dc.contributor.authorViyada Wachtengen_US
dc.contributor.authorShogo Nobukawaen_US
dc.contributor.authorMasayuki Yamaguchien_US
dc.contributor.otherJapan Advanced Institute of Science and Technologyen_US
dc.contributor.otherMahidol Universityen_US
dc.date.accessioned2018-11-23T09:55:40Z
dc.date.available2018-11-23T09:55:40Z
dc.date.issued2015-11-05en_US
dc.description.abstract© 2015 Elsevier Ltd.All rights reserved. Interphase transfer of di-2-ethylhexyl adipate (DOA) between ethylene-propylene copolymer (EPR) and polyisobutylene (PIB) in the laminated sheets was studied. It was found that the amount of DOA in each phase is determined by the ambient temperature. DOA moved to EPR from PIB at -20 °C and vice versa at 40 °C, when the DOA content before lamination was 10 phr. This is attributed to the change of interaction parameters between DOA and each rubber as a function of temperature. Because of the DOA transfer, the glass transition temperature of each rubber phase changes with the ambient temperature. The phenomenon can be applicable to an all-season tire, when a matrix polymer contains more plasticizer at low temperature and vice versa in a blend with sea-island structure.en_US
dc.identifier.citationPolymer. Vol.78, (2015), 208-211en_US
dc.identifier.doi10.1016/j.polymer.2015.09.079en_US
dc.identifier.issn00323861en_US
dc.identifier.other2-s2.0-84944050079en_US
dc.identifier.urihttps://repository.li.mahidol.ac.th/handle/20.500.14594/35731
dc.rightsMahidol Universityen_US
dc.rights.holderSCOPUSen_US
dc.source.urihttps://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=84944050079&origin=inwarden_US
dc.subjectChemistryen_US
dc.subjectMaterials Scienceen_US
dc.titleInterphase transfer of plasticizer between immiscible rubbersen_US
dc.typeArticleen_US
dspace.entity.typePublication
mu.datasource.scopushttps://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=84944050079&origin=inwarden_US

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