Organic and Biomolecular Chemistry. Vol.1, No.20 (2003), 3495-3497
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Manat Pohmakotr, Pornthep Numechai, Saisuree Prateeptongkum, Patoomratana Tuchinda, Vichai Reutrakul A general synthetic route to 1-azabicyclo[m.n.0]alkenes via cyclisation based on α-sulfinyl carbanions. Organic and Biomolecular Chemistry. Vol.1, No.20 (2003), 3495-3497. doi:10.1039/b308383g Retrieved from: https://repository.li.mahidol.ac.th/handle/20.500.14594/20684
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A general synthetic route to 1-azabicyclo[m.n.0]alkenes via cyclisation based on α-sulfinyl carbanions
A general synthetic route to 1-azabicyclo[m.n.0]alkenes via cyclisation based on α-sulfinyl carbanions was presented. The intramolecular nucleophillic addition of α-sulfinyl carbanions afforded 1-azabicyclo[m.n.0]alkenes in good yields. It is reported that the developed strategy should provide a general solution for the synthesis of various classes of 1-azabicyclic alkaloids.
