Publication:
Asymmetric Synthesis of Trifluoromethylated ent-Fragransin C <inf>1</inf>

Issued Date

2019-03-31

Resource Type

Article

ISSN

10990690
1434193X

DOI

10.1002/ejoc.201801676

Other identifier(s)

2-s2.0-85060334645

Rights

Mahidol University

Rights Holder(s)

SCOPUS

Bibliographic Citation

European Journal of Organic Chemistry. Vol.2019, No.12 (2019), 2212-2223

Suggested Citation

Sasirome Racochote, Manat Pohmakotr, Chutima Kuhakarn, Pawaret Leowanawat, Vichai Reutrakul, Darunee Soorukram Asymmetric Synthesis of Trifluoromethylated ent-Fragransin C <inf>1</inf>. European Journal of Organic Chemistry. Vol.2019, No.12 (2019), 2212-2223. doi:10.1002/ejoc.201801676 Retrieved from: https://repository.li.mahidol.ac.th/handle/20.500.14594/50573

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Title

Asymmetric Synthesis of Trifluoromethylated ent-Fragransin C <inf>1</inf>

Author(s)

Sasirome Racochote
 Manat Pohmakotr
 Chutima Kuhakarn
 Pawaret Leowanawat
 Vichai Reutrakul
 Darunee Soorukram

Other Contributor(s)

Mahidol University

Abstract

© 2019 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim Asymmetric synthesis of trifluoromethylated derivative of ent-fragransin C 1 was reported. The installation of contiguous stereochemistries across the tetrahydrofuran scaffold was achieved through stereocontrolled conjugate addition, aldol reaction, and a protection-free intramolecular C-O bond formation (furan ring formation) via chemoselective generation of the benzylic carbocation.

Keyword(s)

Chemistry

Availability

URI

https://repository.li.mahidol.ac.th/handle/20.500.14594/50573

Collections

Scopus 2019