Publication:
Crystal structure of 4,6-diamino-2,2-dimethyl-3-[3-(2,4,5-trichlorophenoxy)-propoxy]-2,3-dihydro-1,3,5-triazin-1-ium chloride methanol monosolvate

3

Issued Date

2015-01-01

Resource Type

Article

ISSN

20569890

DOI

10.1107/S205698901501378X

Other identifier(s)

2-s2.0-84976474701

Rights

Mahidol University

Rights Holder(s)

SCOPUS

Bibliographic Citation

Acta Crystallographica Section E: Crystallographic Communications. Vol.71, (2015), o608-o609

Suggested Citation

Pattarapol Khongsuk, Samran Prabpai, Palangpon Kongsaeree Crystal structure of 4,6-diamino-2,2-dimethyl-3-[3-(2,4,5-trichlorophenoxy)-propoxy]-2,3-dihydro-1,3,5-triazin-1-ium chloride methanol monosolvate. Acta Crystallographica Section E: Crystallographic Communications. Vol.71, (2015), o608-o609. doi:10.1107/S205698901501378X Retrieved from: https://repository.li.mahidol.ac.th/handle/123456789/35770

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Title

Crystal structure of 4,6-diamino-2,2-dimethyl-3-[3-(2,4,5-trichlorophenoxy)-propoxy]-2,3-dihydro-1,3,5-triazin-1-ium chloride methanol monosolvate

Author(s)

Pattarapol Khongsuk
 Samran Prabpai
 Palangpon Kongsaeree

Other Contributor(s)

Mahidol University

Abstract

In the title methanol-solvated salt, C14H19Cl3N5O2+·Cl-·-CH3OH, the triazine molecule is protonated at one of the triazine N atoms. In the crystal, the triazine cations are linked through a pair of N-H··· N hydrogen bonds, with graph-set R22(8), forming an inversion dimer. The protonated N atom and the 2- and 4-amino groups of the triazine cation interact with the chloride anion through N-H···Cl hydrogen bonds, leading to the formation of a tape structure running along the b-axis direction. A short Cl···Cl contact [3.2937 (9) Å] is observed in the tape. The methanol molecule is linked to the chloride anion and the triazine cation, respectively, by an O-H···Cl hydrogen bond and a C-H···O interaction.

Keyword(s)

Chemistry
 Materials Science

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URI

https://repository.li.mahidol.ac.th/handle/123456789/35770

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