Publication: Samarium dienolate mediated stereoselective synthesis of anti-1,3-diol monoesters via aldol-Tishchenko reaction
| dc.contributor.author | Vichai Reutrakul | en_US |
| dc.contributor.author | Jaray Jaratjaroonphong | en_US |
| dc.contributor.author | Patoomratana Tuchinda | en_US |
| dc.contributor.author | Chutima Kuhakarn | en_US |
| dc.contributor.author | Palangpon Kongsaeree | en_US |
| dc.contributor.author | Samran Prabpai | en_US |
| dc.contributor.author | Manat Pohmakotr | en_US |
| dc.contributor.other | Mahidol University | en_US |
| dc.date.accessioned | 2018-08-20T06:50:50Z | |
| dc.date.available | 2018-08-20T06:50:50Z | |
| dc.date.issued | 2006-07-03 | en_US |
| dc.description.abstract | The reaction of an (E)-samarium dienolate, generated by the regioselective reductive cleavage of a phenylsulfonyl activated cyclopropyl ketone with samarium(II) iodide, with aliphatic and aromatic aldehydes gives the 2-substituted anti-1,3-diol monoester derivatives, stereoselectively, in good to excellent yields. The results represent the first report of a dienolate in the aldol-Tishchenko reaction and also provide an optically active polyol with (R)-glyceraldehyde. © 2006 Elsevier Ltd. All rights reserved. | en_US |
| dc.identifier.citation | Tetrahedron Letters. Vol.47, No.27 (2006), 4753-4757 | en_US |
| dc.identifier.doi | 10.1016/j.tetlet.2006.04.091 | en_US |
| dc.identifier.issn | 00404039 | en_US |
| dc.identifier.other | 2-s2.0-33744532073 | en_US |
| dc.identifier.uri | https://repository.li.mahidol.ac.th/handle/20.500.14594/23008 | |
| dc.rights | Mahidol University | en_US |
| dc.rights.holder | SCOPUS | en_US |
| dc.source.uri | https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=33744532073&origin=inward | en_US |
| dc.subject | Biochemistry, Genetics and Molecular Biology | en_US |
| dc.subject | Chemistry | en_US |
| dc.subject | Pharmacology, Toxicology and Pharmaceutics | en_US |
| dc.title | Samarium dienolate mediated stereoselective synthesis of anti-1,3-diol monoesters via aldol-Tishchenko reaction | en_US |
| dc.type | Article | en_US |
| dspace.entity.type | Publication | |
| mu.datasource.scopus | https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=33744532073&origin=inward | en_US |