Publication:
PhI(OAc)<inf>2</inf>/KI mediated 1,2-acetoxysulfenylation of alkenes: Facile synthesis of β-acetoxysulfides

Issued Date

2013-10-21

Resource Type

Article

ISSN

14645416
00404020

DOI

10.1016/j.tet.2013.08.018

Other identifier(s)

2-s2.0-84883487957

Rights

Mahidol University

Rights Holder(s)

SCOPUS

Bibliographic Citation

Tetrahedron. Vol.69, No.42 (2013), 8847-8856

Suggested Citation

Charoensak Muangkaew, Praewpan Katrun, Patcharaphon Kanchanarugee, Manat Pohmakotr, Vichai Reutrakul, Darunee Soorukram, Thaworn Jaipetch, Chutima Kuhakarn PhI(OAc)<inf>2</inf>/KI mediated 1,2-acetoxysulfenylation of alkenes: Facile synthesis of β-acetoxysulfides. Tetrahedron. Vol.69, No.42 (2013), 8847-8856. doi:10.1016/j.tet.2013.08.018 Retrieved from: https://repository.li.mahidol.ac.th/handle/20.500.14594/31187

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Title

PhI(OAc)<inf>2</inf>/KI mediated 1,2-acetoxysulfenylation of alkenes: Facile synthesis of β-acetoxysulfides

Author(s)

Charoensak Muangkaew
 Praewpan Katrun
 Patcharaphon Kanchanarugee
 Manat Pohmakotr
 Vichai Reutrakul
 Darunee Soorukram
 Thaworn Jaipetch
 Chutima Kuhakarn

Other Contributor(s)

Mahidol University

Abstract

A convenient method for 1,2-acetoxysulfenylation of alkenes using disulfide promoted by (diacetoxyiodo)benzene (PhI(OAc)2, DIB)/KI was developed. The reaction is highly regioselective for styrene derivatives while aliphatic alkenes lead to a mixture of two regioisomers. © 2013 Elsevier Ltd. All rights reserved.

Keyword(s)

Biochemistry, Genetics and Molecular Biology
 Chemistry
 Pharmacology, Toxicology and Pharmaceutics

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URI

https://repository.li.mahidol.ac.th/handle/20.500.14594/31187

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